Mine are:
1.Nathan and Haley
2.Stefan and Elena
3.Chuck and Blair
4.Tyler and Caroline
5.Lucas and Peyton
6.Liam and Annie
7.Booth and Bones
8.Mark and Lexie
9.Sawyer and Kate
10.Barney and Robin

I don't think I have that many ^^

Damon&Elena
Spike&Buffy
Lucas&Peyton
Nathan&Haley
Phoebe&Cole
Klaus&Caroline
Cas&Meg
Chuck&Blair
Michael&Sarah
Jason&Jessica

Mine are:

1. Barney and robin
2. Luke and lorelai
3. Jess and Rory
4. Lucas and peyton
5. Jimmy and Sabrina
6. Baze and cate
7. Liam and Annie
8. Sawyer and Kate
9. Nathan and Hayley
10. Logan and veronica

1.Damon and Elena
2.Stefan and Katherine
3.Tyler and Caroline
4.Penny and Sheldon
5.Barney and Robin
6.Mercedes and Riley (DON'T HATE ON ME!)
7.Jeremy and Anna
8.Jenna and Alaric
9.Marshall and Lily
10.Liam and Annie

1. Chuck and Blair
2. Kurt and Blaine
3. Hyde and Jackie
4. Chandler and Monica
5. Nick and Jess
6. Santana and Brittany
7. Serena and Nate
8. Tate and Violet
9. Sam and Quinn
10. Tony and Ziva

1_Sawyer and Kate (LoST)
2-3_The Doctor and Rose (Doctor Who); Lee and Kara (BSG)
4-5_Ross and Rachel (Friends); Luke and Lorelai (Gilmore Girls)
6_Lyla and Tim (FNL)
7_Sookie and Eric (True Blood)
8_Lily and Cullen (Hell on Wheels)
9_Jackie and Hyde (Thats 70 show)
10_Aeryn and Jonh (Farscape)

Mine :
1. Leyton
2. Chair
3. Jate
4. Joey/Pacey
5. Monica/Chandler
6. Damon and Bonnie
7. Amy and Ricky
8. Leah and Daniel
9. Naley
10. Brulian

Leyton and Chair is really close to each other,but Leyton is a bit before

1. Brian & Justin (Queer As Folk)
2. Lee & Kara (Battlestar Galactica)
3. Logan & Veronica (Veronica Mars)
4. Doctor & Rose (Doctor Who)
5. John & Cameron (Terminator: The Sarah Connor Chronicles)
6. Pacey & Joey (Dawson's Creek)
7. Rory & Jess (Gilmore Girls)
8. Buffy & Spike (Buffy the Vampire Slayer)
9. Freddie & Effy (Skins)
10. Nancy & Andy (Weeds)

Nathan and Haley
Damon and Elena
Mark and Lexie
Monica and Chandler
Spencer and Toby
Pacey and Joey
Wade and Zoe
Dan and Blair
Michael and Sara
Klaus and Caroline

Pacey and Joey
Logan and Veronica
Spike and Buffy
Klaus and Caroline
Tim and Lyla
Lexie and Mark
Emily and Daniel
Evan and Casey
Kai and Erica
Marian and Guy

Chuck and Blair
Damon and Elena
Jack and Kate
Doug and Carol
Tate and Violet
Tyler and Caroline
Ezra and Aria
Carrie and Big
Monica and Chandler
Spike and Buffy

Klaus and Caroline
Damon and Bonnie
Merlin and Morgana
Derek and Stiles
Toby and Spencer
Nate and Jenny
Jason and Aria
Gendry and Arya
Ryan and Marissa
Seth and Summer

1.brooke and lucas (One tree Hill)
2.Marissa and Ryan (The o.c)
3.Dan and Serena/Blair and Chuck
4.Toby and Spencer (pretty Little Lars)
5. Jess and rory(Gilmore Girls)
6.navid and Silver (90210)
7.nathan and Harley (One tree Hill)
8.summer and Seth (The o.c)
9.jake and Peyton (One tree Hill)
10.damon and elena (TVD)

1. Buffy & Angel (Buffy the Vampire Slayer)
2. Damon & Elena (The Vampire Diaries)
3. Rumpelstilstkin/Mr. Gold & Belle (Once Upon a Time)
4. Donna & Harvey (Suits)
5. Veronica & Logan (Veronica Mars)
6. Brooke & Lucas (One Tree Hill)
7. Marshall & Lily (How I Met Your Mother)
8. Brennan & Booth (Bones)
9.Rory & Logan (Gilmore Girls)
10. Dani & Nico (Necessary Roughness)

1. Peyton & Lucas
2. Veronica & Logan
3. Elena & Damon
4. Joey & Pacey
5. Effy & Freddie
6. Rory & Jess
7. Buffy & Spike
8. Sookie & Eric
9. Blair & Chuck
10. Kate & Sawyer

{1} Lucas/Peyton {One Tree Hill}
{2} Sawyer/Juliet {Lost}
{3} Nathan/Haley {One Tree Hill}
{4} Neal/Sara {White Collar}
{5} Jack/Kate {Lost}
{6} Barney/Robin {How I Met Your Mother}
{7} Tyler/Caroline {The Vampire Diaries}
{8} Damon/Elena {The Vampire Diaries}
{9} Derek/Meredith {Grey's Anatomy}
{10} Mark/Addison {Grey's Anatomy}

1.Lucas/Peyton (One Tree Hill)
2.Ross/Rachel (Friends)
3.Luke/Lorelai (Gilmore Girls)
4.Chuck/Blair (Gossip Girl)
5.Freddie/Effy (Skins Generation 2)
6.Stefan/Elena (The Vampire Diaries)
7.Alex/Izzie (Grey's Anatomy)
8.Michael/Nikita (Nikita)
9.Nathan/Haley (One Tree Hill)
10.Navid/Adrianna (90210)

1.aria and ezra
2. andy and prue
3. emily and maya
4. booth and brenan
5.stefan and elena
6.barney and robin
7.sam and quenn
8.kurt and blain
9.caleb and hanna
10.jeremy and anna

These are all current ships, not past ships b/c I have too many:
1) Sookie/Eric (True Blood)
2) Damon/Elena (TVD)
3) Zoe/Wade (Hart of Dixie)
4) Tyler/Caroline (TVD)
5) Chuck/Blair and Dan/Serena (Gossip Girl)
6) Sheldon/Amy (Big Bang Theory)
7) Tessa/Ryan (Suburgatory)
8) Jenna/Matty (Awkward)
9) Barney/Robin (HIMYM)
10) Rumpel/Belle

Honorable Mention: 11) Matthew/Mary (Downton Abbey)

ETA: Ha, my ships changed again. Recently got into OUAT and I'm shipping Rumbelle.

1. Damon/Elena (The Vampire Diaries)
2. Kurt/Blaine (Glee)
3. Brian/Justin (Queer As Folk)
4. Mark/Lexie (Grey’s Anatomy)
5. Barney/Robin (How I Met Your Mother)
6. Klaus/Caroline (The Vampire Diaries)
7. Tony/Ziva (NCIS)
8. Pacey/Joey (Dawson's Creek)
9. Chuck/Blair (Gossip Girl)
10. Sookie/Eric (True Blood)

1. Damon/Elena (TVD)
2. Angel/Buffy (BTVS)
3. Chuck/Blair (GG)
4. Booth/Brennan (Bones)
5. Castle/Beckett (Castle)
6. Daniel/Kate (Perception)
7. Snow/Charming (OUAT)
8. Piper/Leo (Charmed)
9. Ezra/Aria (PLL)
10. Rumpelstilstkin (Mr. Gold)/Belle (OUAT)

I actually have a lot more but these are my top 10

1. Chuck/Blair (Gossip Girl)
2. Seth/Summer (The O.C)
3. Nathan/Haley (One Tree Hill)
4. Joey/Pacey (Dawson's Creek)
5. Brooke/Julian (One Tree Hill)
6. Monica/Chandler (Friends)
7. Ross/Rachel (Friends)
8. Peyton/Lucas & Brooke/Lucas (One Tree Hill) -I like them evenly.
9. Stefan/Elena (The Vampire Diaries)
10. Ryan/Marissa (The O.C)

1. Damon & Elena (TVD)
2. Chuck & Blair (GG)
3. Lucas & Peyton (OTH)
4. Stefan & Katherine (TVD)
5. Effy & Freddie (Skins)
6. Booth & Bones (Bones)
7. Sawyer & Juliet (Lost)
8. Sawyer & Kate (Lost)
9. Spike & Buffy (BTVS)
10. Owen & Cristina (G's A)

1) Nathan & Haley (One Tree Hill)
2) Stefan & Elena (The Vampire Diaries)
3) Clark & Lois (Smallville)
4) Ryan & Taylor (The OC)
5) Barney & Robin (How I Met Your Mother)
6) Finn & Rachel (Glee)
7) Toby & Spencer (Pretty Little Liars)
8) Lucas & Peyton (One Tree Hill)
9) Nate & Serena (Gossip Girl)
10) Seth & Summer (The OC)

1. Lucas & Peyton
2. Clark & Lana
3. Jack & Kate
4. Ryan & Marissa
5. Seth & Summer
6. Piper & Leo
7. Nathan & Haley
8. Buffy & Angel
9. Buffy & Spike
10. Desmond & Penny

1) Damon & Elena
2) Freddie & Effy
3) Sherlock & Irene
4) Neal & Emma
5) Sawyer & Kate

Jesse & Rachel
Monica & Chandler
Charlie & Claire
Snow & Charming
Finn & Rachel

1. Macy & Harry (Charmed 2018)
2. Toby & Happy (Scorpion)
3. Tony & Ziva (NCIS)
4. David & Patrick (Schitt's Creek)
5. Olivia & Barba (Law and Order: SVU)
6. Chris & Street (SWAT)
7. Jack & Sam (Stargate SG-1)
8. Niles & Daphne (Frasier)
9. Maddie & Chimney (911)
10. Sheldon & Amy (The Big Bang Theory)